Synthesis and characterization of three-coordinate and related beta-diketiminate derivatives of manganese, iron, and cobalt

Research has been conducted on the coordinate complexes. The reaction of M{N(SiMe (sub)3) (sub)2} (sub)2 (M= Mn, Re, Co) with different beta-diketimines has produced three-coordinate complexes characterized via magnetic measurements, X-ray crystallography and NMR and IR spectroscopy and the details are included.