Effect of geminal substitution on the strain energy of dioxiranes. Origin of the low ring strain of dimethyldioxirane

Authors :: Bach, Robert D.
Dmitrenko, Olga
Source :: Journal of Organic Chemistry. May 31, 2002, Vol. 67 Issue 11, p3884, 13 p.
Publication Year :: 2002
Abstract: Research has been conducted on the dioxirane dimethyldioxirane. The strain energies of these dioxiranes have been investigated via the use of the high-level computational schemes and the dioxirane reactivity towards alkenes has been predicted.

Subjects :: Chemistry, Organic -- Research
Ethylene oxide -- Physiological aspects
Ring formation (Chemistry) -- Physiological aspects
Cyclic compounds -- Physiological aspects
Olefins -- Physiological aspects
Biological sciences
Chemistry

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