Trialkylphosphine-stabilized copper-phenyltellurolate complexes: from small molecules to nanoclusters via condensation reactions

Authors :: DeGroot, Marty W.
Cockburn, Michael W.
Workentin, Mark S.
Corrigan, John F.
Source :: Inorganic Chemistry. August 27, 2001, Vol. 40 Issue 18, p4678, 8 p.
Publication Year :: 2001
Abstract: Research has been conducted on the reactions of CuCl with Te(Ph)SiMe (sub)3 and solublizing trialkylphosphine ligands. Results indicate that these reactions produce structurally characterized polynuclear copper-phenyltellurolate complexes and that the complex formation depend on the ancillary phosphine ligand.

Subjects :: Chemistry, Inorganic -- Research
Copper -- Physiological aspects
Coordination compounds -- Physiological aspects
Molecules -- Models
Ligands -- Physiological aspects
Chlorine -- Physiological aspects
Solution (Chemistry) -- Physiological aspects
Tellurium -- Physiological aspects
Silicon -- Physiological aspects
Chemistry

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