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The C-Acylation of Trilithiated Acetoacetanilides Followed by Cyclization and Rearrangements to 3-Aryl-5-Aminoaryl-2H-Pyran-2-Ones

Authors :
Downs, Jennifer R.
Grant, Sally P.
Townsend, Jessica D.
Pastine, Stefan J.
Embree, Mildred C.
Metz, Clyde R.
Walsch, Rosa D. Bailey
Pennington, William T.
Beam, Charles F.
Source :
Bulletin of the South Carolina Academy of Science. Annual 2001, p70, 2 p.
Publication Year :
2001

Abstract

The initially perceived routine condensation of trilithiated acetoacetanilides with several benzoate esters did not give the anticipated C-acylated or cyclized 4-pyranone product. A 2-pyranone resulting from several rearrangements of the [...]

Details

Language :
English
ISSN :
0096414X
Database :
Gale General OneFile
Journal :
Bulletin of the South Carolina Academy of Science
Publication Type :
Academic Journal
Accession number :
edsgcl.80160107