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Ultrasensitive Detection of [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] Using a Microcantilever Sensor
- Source :
- Analytical Chemistry. April 1, 2001, Vol. 73 Issue 7, 1572
- Publication Year :
- 2001
-
Abstract
- Microcantilevers modified with a self-assembled monolayer respond sensitively to specific ion concentrations. Here, we report the detection of trace amounts of [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] using microcantilevers modified with a self-assembled monolayer of triethyl-12-mercaptododecylammonium bromide. The self-assembled monolayer was prepared on a silicon microcantilever coated with a thin layer of gold on one side. The microcantilever undergoes bending due to sorption of [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] ions on the monolayer-modified side. It was found that a concentration of [10.sup.-9] M [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] call be detected using this technology in a flow cell. Other anions, such as [Cl.sup.-], [Br.sup.-], [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII], and [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII], have minimal effect on the deflection of this cantilever. The mechanics of the bending and the chemistry of cantilever modification are discussed.
- Subjects :
- Ions -- Research
Bromides -- Usage
Chemistry
Subjects
Details
- ISSN :
- 00032700
- Volume :
- 73
- Issue :
- 7
- Database :
- Gale General OneFile
- Journal :
- Analytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.73828324