Hydrothermal syntheses: a route to the stepwise condensation of reduced Keggin polyanions. From reduced beta-[H (sub) m SiMo (sub)12 O (sub)40] (super)n- monomers to bicapped dimerized [Si (sub)2 Mo (sub)28 O (sub)84 (H (sub)2 O) (sub)2] (super)6- anions

Authors :: Dolbecq, Anne
Cadot, Emmanuel
Eisner, Dirk
Secheresse, Francis
Source :: Inorganic Chemistry. Sept 20, 1999, Vol. 38 Issue 19, p4217, 7 p.
Publication Year :: 1999
Abstract: A synthesis of five reduced polyoxomolybdate anions is presented. The use of IR spectroscopy, hydrothermal reactions and redox titrations is described.

Subjects :: Chemistry, Inorganic -- Research
Anions -- Research
Monomers -- Research
Spectrum analysis -- Usage
Chemistry

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