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Effect of position of polyether attachment on the electron self-exchange activation barrier energies of redox polyether hybrid molten salts

Authors :
Dickinson, Enders
Masui, Hitoshi V.
Williams, Mary Elizabeth
Murray, Royce W.
Source :
Journal of Physical Chemistry B. Dec 16, 1999, Vol. 103 Issue 50, p11028, 8 p.
Publication Year :
1999

Abstract

Results show that activation of homogeneous electron transfers in molten salts encounter large activation barriers. Data further indicate that physical diffusion rates and viscosity is dependent on the number of ethylene oxide segments in the polyether tails.

Details

ISSN :
15206106
Volume :
103
Issue :
50
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry B
Publication Type :
Academic Journal
Accession number :
edsgcl.59572938