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19F and 1H magnetic relaxation dispersion determination of the translation encounter between ionic salts and nitroxide free radicals in aqueous solution

Authors :
Dinesen, T.R.J.
Seymour, J.
McGowan, L.
Wagner, S.
Bryant, R.G.
Source :
Journal of Physical Chemistry A. Feb 18, 1999, Vol. 103 Issue 7, p782, 5 p.
Publication Year :
1999

Abstract

A study was conducted to analyze the translation encounter between ionic salts and nitroxide free radicals in aqueous solution. Relaxation time measurements were carried out as a function of magnetic field strength. The pH was adjusted based on the aliquots of dilute acid or base. Results indicated that magnetic relaxation data is not enough to generate a detailed characterization of local electrostatic fields between solutes.

Details

ISSN :
10895639
Volume :
103
Issue :
7
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.54223277