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Electrode modification from the electrolysis of (M(bipyridine)3)(ClO4)2(M = Co(super II), Fe(super II), and Ru(super II)) in media of low dielectric constant. Electrocatalytic behavior and an amperometric C60 sensor

Electrode modification from the electrolysis of (M(bipyridine)3)(ClO4)2(M = Co(super II), Fe(super II), and Ru(super II)) in media of low dielectric constant. Electrocatalytic behavior and an amperometric C60 sensor

Authors :
Winkler, Krzystof
Costa, David A.
Hayashi, Akari
Balch, Alan L.
Source :
Journal of Physical Chemistry B. Nov 26, 1998, Vol. 102 Issue 48, p9640, 7 p.
Publication Year :
1998

Abstract

A study was conducted to analyze the voltammetric characteristics of transition metal complexes of 2,2'-bipyridine, (M(bipyridine)3)(ClO4)2(M = Co(super II), Fe(super II), and Ru(super II)), in toluene/acetonitrile mixtures using cyclic voltammetry. Experimental results indicated that the reduction current related to square wave voltammetric experiments increased linearly with the C60 concentration between the range of 0.25 - 20 micron.

Details

ISSN :
15206106
Volume :
102
Issue :
48
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry B
Publication Type :
Academic Journal
Accession number :
edsgcl.54036200