Rhodium-catalyzed arylzincation of terminal allenes providing allylzinc reagents and its application to versatile three-component coupling reaction

Authors :: Yoshida, Yuji
Murakami, Kei
Yorimitsu, Hideki
Oshima, Koichiro
Source :: Journal of the American Chemical Society. July 7, 2010, Vol. 132 Issue 26, 8878-8879
Publication Year :: 2010
Abstract: Rhodium-catalyzed regioselective arylzincation of terminal allenes is performed to obtain synthetically useful functionalized allylzinc reagents. The obtained allylzinc reagents react with a variety of electrophiles such as acetonitrile to offer a more versatile three-component coupling reaction.

Subjects :: Acetonitrile -- Chemical properties
Acetonitrile -- Electric properties
Catalysis -- Analysis
Organometallic compounds -- Structure
Organometallic compounds -- Chemical properties
Rhodium -- Chemical properties
Zinc -- Chemical properties
Zinc -- Electric properties
Chemistry

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