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Reactions of nucleophiles with perfluoro[2.2]paracyclophane

Authors :
Lianhao Zhang
Ogawa, Katsu
Ghiviriga, Ion
Dolbier, William R., Jr.
Source :
Journal of Organic Chemistry. Sept 4, 2009, Vol. 74 Issue 17, 6831-6836
Publication Year :
2009

Abstract

The aromatic rings of perfluoro[2.2]paracyclophane are reactive with respect to nucleophilic substitution reactions. The reactions have proceeded via [S.sub.N]Ar mechanisms and the reactivity issues are discussed including the effect of substituents on reactivity and regiochemistry of substitution.

Subjects

Subjects :
Cyclopropane compounds -- Chemical properties
Cyclopropane compounds -- Structure
Hydroxides -- Chemical properties
Nucleophiles -- Structure
Nucleophiles -- Chemical properties
Substitution reactions -- Analysis
Thiols -- Chemical properties
Biological sciences
Chemistry

Details

Language :
English
ISSN :
00223263
Volume :
74
Issue :
17
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.222276894

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