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Syntheses and structural characterizations of two three-dimensional polymers: (super 3)(sub infinity)(((n-C4H9)3Sn)3M(CN)6) (M = Fe, Co)

Authors :
Niu, Tianyan
Lu, Jian
Wang, Xiqu
Korp, James D.
Jacobson, Allan J.
Source :
Inorganic Chemistry. Oct 5, 1998, Vol. 37 Issue 20, p5324, 5 p.
Publication Year :
1998

Abstract

A study was conducted on the three-dimensional coordination polymers (((n-C4H9)3Sn(super IV))3M(CN)6) (M = Fe, Co). Synthesis of the polymers involved the slow interdiffusion of aqueous solutions of K3(M(CN)6) and the THF solutions of (C4H9)3SnCl. X-ray crystal structures were also determined and compared with those of ((Me3Sn)3Co(CN)6) and other known organotincyanometalate structures.

Subjects

Subjects :
Polymers -- Research
Chemistry

Details

ISSN :
00201669
Volume :
37
Issue :
20
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.21274415