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Supramolecular architecture in nickel(II) polyamine tetracyanoquinodimethanido systems
- Source :
- Inorganic Chemistry. Dec 31, 1998, Vol. 36 Issue 27, p6390, 7 p.
- Publication Year :
- 1998
-
Abstract
- A study on the synthesis, crystal structure and chemical properties of three different metallic fragments with (NiLN)(super 2+) and (TCNQ)(sub 2)(super 2-) is presented. The metallic fragments are (Ni(dien)2)(super 2+), (Ni(trien))(super 2+) and (Ni(cyclam))(super 2+). Results show that the interaction between TCNQ and the metallic fragments depends on the metal environment in the transition metal center. Hydrogen bonds between the TCNQ nitriles and the amine groups of the metal fragments stabilizes the supramolecular architecture.
Details
- ISSN :
- 00201669
- Volume :
- 36
- Issue :
- 27
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20999114