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Solution photophysics, one-electron photooxidation, and photoinitiated two-electron oxidation of molybdenum(III) complexes
Solution photophysics, one-electron photooxidation, and photoinitiated two-electron oxidation of molybdenum(III) complexes
- Source :
- Inorganic Chemistry. June 1, 1998, Vol. 37 Issue 11, p2779, 7 p.
- Publication Year :
- 1998
-
Abstract
- Studies show that the three (Me3[9]aneN3)MoIIIX3 complexes phosphoresce and undergo photooxidation in solution at room temperature. C(NO2)4 was also found to promote the permanent one-electron photooxidation of (Me3[9]aneN3)MoIIIBr3 and (Me3[9]aneN3)MoIIII3. In the presence of water, disproportionation of photogenerated MoIV intermediates promotes the two-electron oxidation of the complexes.
Details
- ISSN :
- 00201669
- Volume :
- 37
- Issue :
- 11
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20884279