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Organo-selenium induced radical ring-opening intramolecular cyclization or electrophilic cyclization of 2- (arylmethylene) cyclopropylaldehyde: a tunable synthesis of 1-naphthaldehydes or 3-oxabicyclo[3.1.0]hexan-2-ols

Authors :
Maozhong Miao
Xian Huang
Source :
Journal of Organic Chemistry. August 7, 2009, Vol. 74 Issue 15, 5636-5639
Publication Year :
2009

Abstract

1-Naphthaldehydes and 3-oxabicyclo[3.1.0]hexan-2-ols is prepared by the intramolecular alkylation and cyclization of (E)-2-(arylmethylene)cyclopropylaldehyde mediated by different organo-selenium reagents. The properties of selenium reagents have played a major role in the reactions.

Details

Language :
English
ISSN :
00223263
Volume :
74
Issue :
15
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.208250081