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Origin of the reactivity differences of substituted aziridines: Cn vs CC bond breakages
- Source :
- Journal of Organic Chemistry. August 7, 2009, Vol. 74 Issue 15, 5244-5249
- Publication Year :
- 2009
-
Abstract
- The reaction courses of possible ring-opening reactions accompanied by the attack of a nucleophile for different substituent patterns of the aziridine are examined. The results have helped in understanding the mechanisms of different ring-opening reactions and have explained how the kinetics and thermodynamics of the reaction are affected by substituents, which has predicted substitution patterns that steer the reaction course to either CN or CC bond cleavage.
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 74
- Issue :
- 15
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.208159981