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Hydride and gold(triphenylphosphine) derivatives of hexarhenium carbido octadecacarbonyl
- Source :
- Inorganic Chemistry. May 18, 1998, Vol. 37 Issue 10, p2520, 5 p.
- Publication Year :
- 1998
-
Abstract
- Addition of Au(PPh3)Cl to (NEt4)3(HRe6C(CO)18) resulted into (NEt4)2(HRe6C(CO)18(AuPPh3)) while utilizing Au(PPh3)NO3 produced (NEt4)(HRe6C(CO)18(AuPPh3)2). The latter compound was deprotonated by NEt3 to produce (NEt4)2(Re6C(CO)18(AuPPh3)2), which can also be produced by treating either (NEt4)3(HRe6C(CO)18) or (NEt4)2(H2Re6C(CO)18) with 2 equiv of Au(PPh3)Cl in the presence of the strong base DBU.
- Subjects :
- Gold compounds -- Research
Carbonyl compounds -- Research
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 37
- Issue :
- 10
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20810519