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Template synthesis, properties, and crystal structure of a trigonal bipyramidal cobalt(II) octaazamacrobicylic complex
- Source :
- Inorganic Chemistry. Nov 19, 1997, Vol. 36 Issue 24, p5651, 4 p.
- Publication Year :
- 1997
-
Abstract
- A cobalt(II) complex was synthesized from the template condensation of tris(2-aminoethyl)-amine and formaldehyde in the presence of cobalt(II) ion. The product is an encapsulating macrobicyclic ligand, 4,14,19-tris(methoxymethyl)-1,4,6,9,12,14,19,21-octaazabicyclo [7.7.7]tricosane. X-ray crystallography revealed that the cobalt ion exhibit a trigonal bipyramidal geometry.
- Subjects :
- Coordination compounds -- Research
Ligands -- Research
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 36
- Issue :
- 24
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20527722