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Cyclopentadienyl ligand effects on enthalpies of protonation of the Ru-Ru bond in Cp'sub2Rusub2(CO)sub4 complexes
- Source :
- Inorganic Chemistry. Dec 17, 1997, Vol. 36 Issue 26, p6000, 9 p.
- Publication Year :
- 1997
-
Abstract
- Basicities of metal within mononuclear organometallic compounds act as indictors of other reactivities. The basicities of the metal-metal bonds in a set of Cp'sub2Rusub2(CO)sub4 compounds containing several cyclopentadienyl-type ligands, are reported, using titration calorimetry. They are defined as the enthalpies of protonation (DeltaHMHM) of metal compounds with triflic acid (CFsub3SOsub3H) with 1,2-dichlorethane solution.
- Subjects :
- Acids -- Basicity
Organometallic compounds -- Observations
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 36
- Issue :
- 26
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20464100