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Radical hydrostannylation, Pd(O)-catalyzed hydrostannylation, stannylcupration of propargyl alcohols and enynols: Regio- and stereoselectivities
- Source :
- Journal of Organic Chemistry. Oct 31, 1997, Vol. 62 Issue 22, p7768, 13 p.
- Publication Year :
- 1997
-
Abstract
- Radical hydrostannylation (Busub3SnH/AIBN), Pd(O)-catalyzed hydrostannylation (Busub3SnH/Pd(O)) and stannylcupration (BUsub3SN(R)CuCNLisub2) conditions were applied to different enynols and propargyl derivatives. High regio- and stereoselective formation of vinyl- and dienylstannanes were obtained, apart from the radical stannylation reaction.
Details
- ISSN :
- 00223263
- Volume :
- 62
- Issue :
- 22
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20428920