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Evaluation of a 512-channel Faraday-strip array detector coupled to an inductively coupled plasma Mattauch--Herzog mass spectrograph
- Source :
- Analytical Chemistry. July 1, 2009, Vol. 81 Issue 13, p5467, 7 p.
- Publication Year :
- 2009
-
Abstract
- A 512-channel Faraday-strip array detector has been developed and fitted to a Mattauch--Herzog geometry mass spectrograph for the simultaneous acquisition of multiple mass-to-charge values. Several advantages are realized by using simultaneous detection methods, including higher duty cycles, removal of correlated noise, and multianalyte transient analyses independent of special skew. The new 512-channel version offers narrower, more closely spaced pixels, providing improved spectral peak sampling and resolution. In addition, the electronics in the amplification stage of the new detector array incorporate a sample-and-hold feature that enables truly simultaneous interrogation of all 512 channels. While sensitivity and linear dynamic range remain impressive for this Faraday-based detector system, limits of detection and isotope ratio data have suffered slightly from leaky p--n junctions produced during the manufacture of the semiconductor-based amplification and readout stages. This paper describes the new 512-channel detector array, the current dominant noise sources, and the figures of merit for the device as pertaining to inductively coupled plasma ionization.
- Subjects :
- Chemical detectors -- Design and construction
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00032700
- Volume :
- 81
- Issue :
- 13
- Database :
- Gale General OneFile
- Journal :
- Analytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.203603144