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Evaluation of a 512-channel Faraday-strip array detector coupled to an inductively coupled plasma Mattauch--Herzog mass spectrograph

Authors :
Schilling, Gregory D.
Ray, Steven J.
Rubinshtein, Amen A.
Felton, Jeremy A.
Sperline, Roger P.
Denton, M. Bonner
Barinaga, Charles J.
Koppenaal, David W.
Hieftje, Gary M.
Source :
Analytical Chemistry. July 1, 2009, Vol. 81 Issue 13, p5467, 7 p.
Publication Year :
2009

Abstract

A 512-channel Faraday-strip array detector has been developed and fitted to a Mattauch--Herzog geometry mass spectrograph for the simultaneous acquisition of multiple mass-to-charge values. Several advantages are realized by using simultaneous detection methods, including higher duty cycles, removal of correlated noise, and multianalyte transient analyses independent of special skew. The new 512-channel version offers narrower, more closely spaced pixels, providing improved spectral peak sampling and resolution. In addition, the electronics in the amplification stage of the new detector array incorporate a sample-and-hold feature that enables truly simultaneous interrogation of all 512 channels. While sensitivity and linear dynamic range remain impressive for this Faraday-based detector system, limits of detection and isotope ratio data have suffered slightly from leaky p--n junctions produced during the manufacture of the semiconductor-based amplification and readout stages. This paper describes the new 512-channel detector array, the current dominant noise sources, and the figures of merit for the device as pertaining to inductively coupled plasma ionization.

Details

Language :
English
ISSN :
00032700
Volume :
81
Issue :
13
Database :
Gale General OneFile
Journal :
Analytical Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.203603144