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Olefinic ozonation electron transfer mechanism
- Source :
- Journal of Organic Chemistry. August 22, 1997, Vol. 62 Issue 17, p5934, 5 p.
- Publication Year :
- 1997
-
Abstract
- The electron transfer reaction mechanism for the ozonations of ammonia, amines, annilines, and p-phenylenediamines was investigated through analysis of oxidation potentials using conventional cyclic voltammetry. Results have shown that the ozonation rate constants for aromatic compounds were relatively smaller than for olefinic compounds due to the larger activation energies required for catalysis of the aromatic ring. The destruction of the aromatic ring was required to generate the radical cations.
Details
- ISSN :
- 00223263
- Volume :
- 62
- Issue :
- 17
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20139635