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Resonance Raman probing of the interaction between dipyridophenazine complexes of Ru(II) and DNA

Authors :
Coates, Colin G.
Jacquet, Luc
McGarvey, John J.
Bell, Steven E.J.
Al-Obaidi, Ala H.R.
Kelly, John M.
Source :
Journal of the American Chemical Society. July 30, 1997, Vol. 119 Issue 30, p7130, 7 p.
Publication Year :
1997

Abstract

Resonance Raman (RR) spectroscopy was used to analyze the interaction between dipyridophenazine complexes of Ru(II) and DNA. The RR spectra derived from the short-lived MLCT excited states of both complexes were compared with those of the longer-lived states of the DNA complexes. The excited state studies were then applied to the delta and lambda enantiomers where the marker band for both appeared at the same frequency with varying relative intensities.

Details

ISSN :
00027863
Volume :
119
Issue :
30
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.20034181