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Direct catalytic asymmetric addition of allyl cyanide to ketones

Authors :
Yazaki, Ryo
Kumagai, Naoya
Shibasaki, Masakatsu
Source :
Journal of the American Chemical Society. March 11, 2009, Vol. 131 Issue 9, 3195-3197
Publication Year :
2009

Abstract

The direct catalytic asymmetric addition of allyl cyanide to ketones with a bimetallic catalytic system comprising (R,R)-Ph-BPE/[Cu[(C[H.sub.3]CN).sub.4]]Cl[O.sub.4]/LiOAr is described. The reaction has proceeded under proton-transfer condition by using soft Lewis acid/hard Bronsted base bifunctional catalysis.

Subjects

Subjects :
Catalysis -- Analysis
Copper compounds -- Chemical properties
Cyanides -- Chemical properties
Ketones -- Chemical properties
Lithium compounds -- Chemical properties
Chemistry

Details

Language :
English
ISSN :
00027863
Volume :
131
Issue :
9
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.200201615

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