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Synthesis and structural characterization of P-functionalized metallacyclophosphazenes

Authors :
Witt, Michael
Roesky, Herbert W.
Noltemeyer, Matthias
Source :
Inorganic Chemistry. July 30, 1997, Vol. 36 Issue 16, p3476, 4 p.
Publication Year :
1997

Abstract

A method of producing the p-functionalized metallacyclophosphazenes [(Me2N)2PN]2VCl2, [(Me2N)2PN]2MoCl3.MeCN and [(Me2N)2PN]2WCL3.MeCN is described which uses the reaction of Cl3VNSiMe3 with the metal nitride halides CL3MoN and Cl3-WN with [(Me2N)2PNH2}2N]+Cl- is described. The electronic structure of CF3-substituted rings are discussed.

Details

ISSN :
00201669
Volume :
36
Issue :
16
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.19936524