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Direct catalytic asymmetric addition of allylic cyanides to ketoimines

Authors :
Yazaki, Ryo
Nitabaru, Tatsuya
Kumagai, Naoya
Shibasaki, Masakatsu
Source :
Journal of the American Chemical Society. Nov 5, 2008, Vol. 130 Issue 44, 14477-14479
Publication Year :
2008

Abstract

A direct catalytic asymmetric addition of allylic cyanides to ketoimines is developed. Facile and divergent conversion of the product has streamlined the synthesis of chiral nitrogen synthons with tetrasubstituted carbon.

Subjects

Subjects :
Catalysis -- Analysis
Cyanides -- Chemical properties
Schiff bases -- Chemical properties
Chirality -- Analysis
Substitution reactions -- Analysis
Chemistry

Details

Language :
English
ISSN :
00027863
Volume :
130
Issue :
44
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.193278307

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