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Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons

Authors :
Perez-Peralta, Nancy
Sanchez, Mario
Martin-Polo, Jesus
Islas, Rafael
Vela, Alberto
Merino, Gabriel
Source :
Journal of Organic Chemistry. Sept 19, 2008, Vol. 73 Issue 18, 7037-7044
Publication Year :
2008

Abstract

The [C.sub.5.sup.2-] skeleton in combination with saturated hydrocarbon fragments is used to obtain a series of planar tetracoordinate carbon molecules in cyclic semisaturated hydrocarbons. The system is the first example of semisaturated cycles containing a planar tetracoordinate carbon stabilized only by electronic factors.

Details

Language :
English
ISSN :
00223263
Volume :
73
Issue :
18
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.188010072