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Coordination chemistry and photoreactivity of the dinitramide ion
- Source :
- Inorganic Chemistry. March 13, 1996, Vol. 35 Issue 6, p1421, 2 p.
- Publication Year :
- 1996
-
Abstract
- The synthesis and characterization of the metal complex of N3O4(super -), fac-Re(bpy)(CO3)(N3O4) are presented. The complex has been prepared by the reaction of KN3O4 with the reactive precursor fac-Re(bpy)(CO)3OSO2CF3 at room temperature in water and recrystallized from hexanes/CH2Cl2. Analysis showed that the complex is extremely photosensitive in solution and decomposes to Re(bpy)(CO3)NO3 and N2O.
Details
- ISSN :
- 00201669
- Volume :
- 35
- Issue :
- 6
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.18329972