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Tetrachloro- and tetrabromostibonium(V) cations: Raman and 19F, 121Sb, and 123Sb NMR spectroscopic characterization and X-ray crystal structures of SbCl4+Sb(OTeF5)6- and SbBr4+Sb(OTeF5)6-
- Source :
- Inorganic Chemistry. Feb 14, 1995, Vol. 35 Issue 4, p929, 14 p.
- Publication Year :
- 1995
-
Abstract
- The syntheses of both the SbCl4+ cation and novel SbBr4+ cation as their Sb(OTeF5)6- salts are described. The compounds were prepared by oxidation of SB(OTeR5)3 with Cl2 and Br2, respectively. The salts were characterized by low-temperature Raman spectroscopy and X-ray crystallography and in solution at ambient temperature by 19F, 121Sb and 123Sb spectroscopy.
Details
- ISSN :
- 00201669
- Volume :
- 35
- Issue :
- 4
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.18160234