Back to Search
Start Over
Pyridine ligand rotation in self-assembled trigonal prisms: evidence for intracage solvent vapor bubbles
- Source :
- Journal of the American Chemical Society. June 18, 2008, Vol. 130 Issue 24, 7629-7638
- Publication Year :
- 2008
-
Abstract
- A study was conducted to examine the counterion effects and the bilinear Eyring plot exhibited by the pyridine edge interchange reaction. The results revealed that the ordinary reaction mechanism, rotation around the Pt-N bond, proceeds after association of the counterion with Pt atom at its fifth ligand.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 130
- Issue :
- 24
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.181003562