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Se(super 77) solid-state NMR spectroscopy and structures of tetramethylammonium pentaselenide and hexaselenide complexes

Authors :
Barrie, Patrick J.
Clark, Robin J.H.
Chung, Duck-Young
Chakrabarty, Debojit
Kanatzidis, Mercouri G.
Source :
Inorganic Chemistry. August 16, 1995, Vol. 34 Issue 17, p4299, 6 p.
Publication Year :
1995

Abstract

A spectroscopic study of the tetramethylammonium pentaselenide and hexaselenide complexes reveals the five prominent selenium sites in (NMe4)2Se5 and the three crystallographically different selenium sites in (NMe4)2Se6. The anionic conformation of (NMe4)2Se5 is identical in solid and solution state. The shielding anisotropies for the alpha and beta selenium sites are larger than for the gamma site.

Details

ISSN :
00201669
Volume :
34
Issue :
17
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.18035242