Back to Search Start Over

Total synthesis of dactomelynes

Authors :
Lee, Eun
Park, Cheol Min
Yun, Jae Sook
Source :
Journal of the American Chemical Society. August 2, 1995, Vol. 117 Issue 30, p8017, 2 p.
Publication Year :
1995

Abstract

Dactomelynes can be successfully synthesized from beta-alkoxyacrylates through two independent radical cyclization reactions. A general synthetic method for stereoselective halides does not exist but the beta-alkoxyacrylates are stereoselective when used as radical acceptors without extraneous steric influence. The beta-alkoxyacrylates are prepared from (-)-diethyl D-tartrate.

Details

ISSN :
00027863
Volume :
117
Issue :
30
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.17921179