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Observation of photochemical C-N bond cleavage in [CH.sub.3][N.sub.3]: a new photochemical route to cyclic [N.sub.3]

Authors :
Larson, Christopher
Yuanyuan Ji
Samartzis, Peter C.
Quinto-Hernandez, Alfredo
Lin, Jim Jr-Min
Tao-Tsung Ching
Chaudhuri, Chanchal
Shih-Huang Lee
Wodtke, Alec M.
Source :
Journal of Physical Chemistry A. Feb 14, 2008, Vol. 112 Issue 6, p1105, 7 p.
Publication Year :
2008

Abstract

The collision free photochemistry of methyl azide [CH.sub.3][N.sub.3] at 193 nm is examined. Findings reveal a maximum translational energy of 60 percent of the available energy.

Details

Language :
English
ISSN :
10895639
Volume :
112
Issue :
6
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.175696074