Rh[Cl.sub.3]-assisted C-H and C-S bond scissions: isomeric self-association of organorhodium(III) thiolato complex. synthesis, structure, and electrochemistry

Authors :: Pramanik, Kausikisankar
Das, Ujjwal
Adhikari, Basab
Chopra, Deepak
Stoeckli-Evans, Helen
Source :: Inorganic Chemistry. Jan 21, 2008, Vol. 47 Issue 2, 429-438
Publication Year :: 2008
Abstract: The synthesis and characterization of saturated cyclometalated rhodium(III) thiolato complex and its spontaneous self-association in solution are described. The synthesis resulted in anti- and syn-rhodium isomers.

Subjects :: Chemical bonds -- Research
Organometallic compounds -- Chemical properties
Oxidation-reduction reaction -- Analysis
Rhodium -- Chemical properties
Chemistry

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