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Synthesis and reactivity of mononuclear anionic pentafluorophenyl compounds of rhodium(I) and iridium(I). X-ray structure of [(P(OPh)3)(sub 2)(C6F5)(sub 2)RhAg(PPh3)]
- Source :
- Inorganic Chemistry. April 12, 1995, Vol. 34 Issue 8, p2153, 7 p.
- Publication Year :
- 1995
-
Abstract
- Several rhodium and iridium substrates undergo arylation with (Ag(C6F5)) or (NBu4)(Ag(C6F5)(sub 2)) to form new anionic complexes which have been isolated as benzyltriphenylphosphonium or tetrabutylammonium salts. Single-crystal X-ray diffraction study shows that the crystals are triclinic having a unit cell of dimension. The rhodium atom is in a square-pyramidal environment, with two C6F5 (cis) and two P(OPh)3 ligands in the square plane and a Ag(PPh3) moiety in the apical position. Furthermore, the complex contains a Rh-Ag bond unsupported by covalent bridges.
Details
- ISSN :
- 00201669
- Volume :
- 34
- Issue :
- 8
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.17438832