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Organotransition-metal metallacarboranes. 37. Paramagnetic iron-cobalt and dicobalt triple-decker sandwich complexes
- Source :
- Inorganic Chemistry. April 12, 1995, Vol. 34 Issue 8, p2058, 10 p.
- Publication Year :
- 1995
-
Abstract
- The spectral analysis of the 29 valence electron (ve) complexes Cp*Fe(Et2C2B3H2-5-R)CoCp* (1a, R = H; 1b, R = Cl; 1c, R = Br) confirm the association between the unpaired electron and iron, suggesting a formal oxidation state of Fe(III). The paramagnetic 31 ve dianion 1a(super 2-) has the unpaired electron on cobalt. The mixed-ligand 29 ve FeCo complex Cp*Fe(Et2C2B3H3)CoCp and the diamagnetic 30 ve dicobalt complexes are also investigated.
- Subjects :
- Complex compounds -- Research
Spectrum analysis -- Observations
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 34
- Issue :
- 8
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.17438808