Spectroscopic and kinetic studies of perturbed trinuclear copper clusters: the role of protons in reductive cleavage of the O-O bond in the multicopper oxidase Fet3p

Authors :: Augustine, Anthony J.
Quintanar, Liliana
Stoj, Christopher S.
Kosman, Daniel J.
Solomon, Edward I.
Source :: Journal of the American Chemical Society. Oct 31, 2007, Vol. 129 Issue 43, 13118-13126
Publication Year :: 2007
Abstract: Several spectroscopic and kinetic studies of the perturbed trinuclear copper clusters (TNC) are conducted to analyze the function of protons in the reductive cleavage of the O-O bond in multicopper oxidase Fet3p.

Subjects :: Copper compounds -- Structure
Copper compounds -- Mechanical properties
Copper compounds -- Spectra
Oxidases -- Structure
Oxidases -- Mechanical properties
Oxidases -- Spectra
Dynamics -- Analysis
Ultraviolet spectroscopy -- Analysis
Chemistry

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