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Agostic interaction in the methylidene metal dihydride complexes [H.sub.2]MC[H.sub.2] (M = Y, Zr, Nb, Mo, Ru, Th, or U)
- Source :
- Journal of Physical Chemistry A. July 19, 2007, Vol. 111 Issue 28, 6420-6424
- Publication Year :
- 2007
-
Abstract
- A series of quantum chemical calculations used to demonstrate the agostic interaction between the metal atom and H(C) in methylidene metal dihydride complexes [H.sub.2]MC[H.sub.2] suggest that the interaction varies with the character of the metal.
Details
- Language :
- English
- ISSN :
- 10895639
- Volume :
- 111
- Issue :
- 28
- Database :
- Gale General OneFile
- Journal :
- Journal of Physical Chemistry A
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.167836671