Thermochemical properties, [[DELTA].sub.f]H degree(298), S degree(298), and [C.sub.p]degree(T), for n-butyl and n-pentyl hydroperoxides and the alkyl and peroxy radicals, transition states, and kinetics for intramolecular hydrogen shift reactions of the peroxy radicals

The analysis of the thermochemistry and trends in kinetic parameters for the hydrogen shift reactions from each carbon in n-butyl and n-pentyl peroxy radicals is presented.