Influence of anions on intervalence charge transfer (IVCT) in mixed-valence dinuclear complexes

Authors :: Fellows, Elizabeth A.
Keene, F. Richard
Source :: Journal of Physical Chemistry B. June 21, 2007, Vol. 111 Issue 24, p6667, 9 p.
Publication Year :: 2007
Abstract: The electrochemical and spectroelectrochemical analysis is done to determine the influence of anions on the IVCT processes in the mixed-valence dinuclear ruthenium and osmium complexes. Results showed significant differences in the two techniques in the order and extent of effects induced by a number of inorganic anions.

Subjects :: Charge transfer -- Analysis
Ruthenium -- Atomic properties
Ruthenium -- Chemical properties
Chemicals, plastics and rubber industries

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