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Mercury-catalyzed rearrangement of ketoximes into amides and lactams in acetonitrile

Authors :
Ramalingan, Chennan
Yong-Tae Park
Source :
Journal of Organic Chemistry. June 8, 2007, Vol. 72 Issue 12, 4536-4538
Publication Year :
2007

Abstract

An acetonitrile solution of mercury(II) chloride found to catalyze efficiently the conversion of a diverse range of ketoximes into their corresponding amides/lactams. It efficiently catalyzes the rearrangement of a variety of acyclic and cyclic ketoximes with good to excellent yields under neutral condition.

Details

Language :
English
ISSN :
00223263
Volume :
72
Issue :
12
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.167449063