1,2,3-triazolate-bridged tetradecametallic transition metal clusters [[M.sub.14][(L).sub.6][O.sub.6][(OMe).sub.16][X.sub.6]] (M = [Fe.sup.III], [Cr.sup.III] and [V.sup.III/IV]) and related compounds: Ground-state spins ranging from S = 0 to S = 25 and spin-enhanced magnetocaloric effect

Authors :: Shaw, Rachel
Laye, Rebecca H.
Jones, Leigh F.
Low, David M.
Talbot-Eeckelaers, Caytie
Qiang Wei
Milios, Constantinos J.
Teat, Simon
Helliwell, Madeleine
Raftery, James
Evangelistic, Marco
Affronte, Marco
Collison, David
Brechin, Euan K.
Mcinnes, Eric J.L.
Source :: Inorganic Chemistry. June 11, 2007, Vol. 46 Issue 12, p4968, 11 p.
Publication Year :: 2007
Abstract: The synthesis, X-ray structures, and magnetic properties of a family of [[M.sub.14][(L).sub.6][O.sub.6][(OMe).sub.16][X.sub.6]] cluster where (M = [Fe.sup.III], [Cr.sup.III] and [V.sup.III/IV]) is reported.

Subjects :: Transition metals -- Chemical properties
Transition metals -- Structure
Transition metals -- Magnetic properties
Azo compounds -- Chemical properties
Azo compounds -- Magnetic properties
Crystals -- Structure
Crystals -- Research
Chemistry

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