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Effect of pressure on the selectivity for the esterification of ethylene glycol with propionic acid in supercritical C[O.sub.2]

Authors :
Jicheng Zhang
Tao Jiang
Buxing Han
Anlian Zhu
Xiumin Ma
Yinxi Zhou
Liang Bai
Hongwei Xiang
Yongwang Li
Source :
Journal of Physical Chemistry B. May 17, 2007, Vol. 111 Issue 19, 5322-5325
Publication Year :
2007

Abstract

A study was conducted to investigate the esterification of ethylene glycol with propionic acid in supercritical C[O.sub.2] at 50 degree Celsius. The solvent power of C[O.sub.2] for the diester is found to be stronger than that for the monoester because C[O.sub.2] is a nonpolar solvent and polarity of the monoester is stronger than that of the diester.

Details

Language :
English
ISSN :
15206106
Volume :
111
Issue :
19
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry B
Publication Type :
Academic Journal
Accession number :
edsgcl.166174297