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Generation and characterization of the anionic, neutral, and cationic iron-dioxygen adducts (FeO2) in the gas phase
- Source :
- Inorganic Chemistry. Oct 26, 1994, Vol. 33 Issue 22, p5094, 7 p.
- Publication Year :
- 1994
-
Abstract
- Generation of anionic and cationic iron-dioxygen adducts (FeO2) in the gas phase involves chemical ionization of a mixture of Fe(CO)5 and O2. Neutralization reionization mass spectrometry helps generate neutral FeO2 molecules from the cation or anion. Mass spectrometric techniques help characterize all these adducts. (FeO2)+ exhibits isomerism and the isomers are side-on and end-on complexes. Ab initio calculation help analyze the interconversion and energetics of both isomers, and the side-on complex exhibits higher stability than the end-on complex.
- Subjects :
- Oxygen -- Physiological transport
Ferric oxide -- Research
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 33
- Issue :
- 22
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.16538240