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Acidities and homolytic bond dissociation enthalpies (BDEs) of the acidic H-A bonds in acyclic and cyclic alkoxycarbonyl compounds (esters and carbamates)
- Source :
- Journal of Organic Chemistry. Oct 21, 1994, Vol. 59 Issue 21, p6456, 3 p.
- Publication Year :
- 1994
-
Abstract
- A comparative study reveals the higher equilibrium of C-H bond acidities of three cyclic carboxylic esters having alkoxycarbonyl group locked in an E conformation than those of their acyclic analogues. N-H acidity of acyclic carbamates having alkoxycarbonyl group locked in an E conformation is higher than that of acyclic analogous. However, the structural changes exhibit no influence on the bond dissociation energies of the acidic C-H or N-H bonds in the esters or carbamates.
Details
- ISSN :
- 00223263
- Volume :
- 59
- Issue :
- 21
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.16504390