Photodechlorination of Aroclor 1254 in a pilot-scale flow through photoreactor

A novel pilot-scale flow through photoreactor has been designed with the intent to apply it in the field. The photoreactor uses a new plastic coil, instead of the conventional quartz tube. The photoreactor consists of six ultraviolet (UV) lamps with five around the coil and one at the center. Laboratory investigations were conducted using the photoreactor to treat neat Aroclor 1254 in alkaline isopropanol (IPA). The photoreaction is fast and efficient, even though the UV transmittances of the three plastic tubes investigated were lower than that of quartz. The reaction kinetics of the practical mixtures are explored. An analysis of five different constituent congeners of Aroclor 1254 indicated that higher congeners dechlorinate producing some of the lower ones, which are subsequently dechlorinated. The dechlorination of Aroclor 1254 was faster when water was added to the alkaline IPA-Aroclor solution. DOI: 10.1061/(ASCE)0733-9372(2007)133:6(646) CE Database subject headings: PCB; Ultraviolet radiation; Degradation; Reactors.