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(Indenyl)cobalt(I)-catalyzed cocyclization of alkyne, alkene, and carbon monoxide to cyclopentenones

Authors :
Lee, Bun Yeoul
Chung, Young Keun
Jeong, Nakcheol
Lee, Youngshin
Hwang, Sung Hee
Source :
Journal of the American Chemical Society. Sept 21, 1994, Vol. 116 Issue 19, p8793, 2 p.
Publication Year :
1994

Abstract

1, 5-cyclooctadiene (indenyl)cobalt(I) complex catalyzes the cyclization of alkyne, alkene and carbon monoxide under mild reaction conditions producing cyclopentenones in good yields. This catalyst helps synthesize cyclopentenones from enzymes and from alkynes with norbornadine or norbornene and this method can be used for large scale production of cyclopentenones.

Details

ISSN :
00027863
Volume :
116
Issue :
19
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.16428060