Thermal control over the topology of cleavage polymers: From linear to hyperbranched structures

Authors :: Chun-Yan Hong
De-Cheng Wu
Cai-Yuan Pan
Source :: Journal of the American Chemical Society. May 2, 2007, Vol. 129 Issue 17, 5354-5355
Publication Year :: 2007
Abstract: Michel-addition polymerization of disulfide-based diacrylate and equimolar N-methyl ethylenediamine (MEDA) has formed ABB' type intermediates. The poly(amino ester)s have stimuli-sensitive disulfide bonds in the backbone that can be cleaved under dithiothreitol (DTT), affording these poly(amino ester)s with potential applications.

Subjects :: Nuclear magnetic resonance spectroscopy -- Analysis
Polyamines -- Chemical properties
Polyamines -- Spectra
Polymerization -- Analysis
Chemistry

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