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A direct observation of a concerted two-bond breaking reaction
- Source :
- Journal of the American Chemical Society. April 4, 2007, Vol. 129 Issue 13, p3784, 2 p.
- Publication Year :
- 2007
-
Abstract
- An affirmative observation of concerted braking of two chemical bonds in the photodissociation of dimethyl sulfoxide (DMSO) is reported. It is concluded that, upon excitation near 200 nm, DMSO decomposes into SO + 2C[H.sub.3] with a quantum yield of approximately 1.5 for the methyl products.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 129
- Issue :
- 13
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.163673925