Six-fold oxygen-coordinated triplet (S=1) palladium(II) moieties templated by tris(bipyridine)ruthenium(II) ions

Authors :: Pointillart, Fabrice
Train, Cyrille
Villain, Francoise
Cartier Dit Moulin, Christophe
Aullon, Gabriel
Alvarez, Santiago
Verdaguer, Michel
Gredin, Patrick
Chamoreau, Lise-Marie
Gruselle, Michel
Source :: Journal of the American Chemical Society. Feb 7, 2007, Vol. 129 Issue 5, 1327-1333
Publication Year :: 2007
Abstract: The syntheses of templated assembly of [[Ru.sup.II][(bpy).sub.3]]- [[Pd.sup.II.sub.2][(ox).sub.3]], Pd2 and [[Ru.sup.II][(bpy).sub.3]][[Pd.sup.II][Mn.sup.II][(ox).sub.3]], PdMn are described. X-ray absorption spectroscopy results revel an unusual 6-fold oxygen environment around the Pd(II) atoms and due to this palladium(II) has a triplet (S=1) ground state.

Subjects :: Palladium -- Chemical properties
Palladium -- Atomic properties
Ruthenium -- Chemical properties
Ruthenium -- Atomic properties
Absorption spectra -- Analysis
Chemistry

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